Silver chlorate: Difference between revisions

Content deleted Content added
No edit summary
Undid revision 1245796478 by Coolscarternomong (talk)
 
(32 intermediate revisions by 25 users not shown)
Line 1:
{{chembox
{{Chembox new
| Verifiedfields = changed
| Name = Silver(I) chlorate
| Watchedfields = changed
| ImageFile = Silver-chlorate-3D-vdW.png
| verifiedrevid = 464390935
<!-- | ImageSize = 200px -->
| Name ImageName = Silver(I) chlorate
| ImageFile ImageFile = Silver-chlorate-3D-vdW.png
| OtherNames = chloric acid silver salt
| ImageName Name = Silver(I) chlorate
| Section1 = {{Chembox Identifiers
| OtherNames = Argentous chlorate
| CASNo = 7783-92-8
| IUPACName = Silver(I) chlorate
| SystematicName = Silver(I) chlorate(V)
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 7991255
| PubChem = 9815505
| InChI = 1/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
| InChIKey = SDLBJIZEEMKQKY-REWHXWOFAI
| SMILES = [Ag+].[O-]Cl(=O)=O
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = SDLBJIZEEMKQKY-UHFFFAOYSA-M
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 7783-92-8
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = O4T3J400JU
| EINECS = 232-034-9
}}
| Section2 = {{Chembox Properties
| Formula = AgClO<sub>3</sub>
| MolarMass = 191.319 g/mol
| Appearance = white crystals
| Density = 4.443 g/cm<sup>3</sup>, solid
| MeltingPtMeltingPtC = 230 °C
| BoilingPtBoilingPtC = 250 °C ''decomp.''
| BoilingPt_notes = (decomposes)
| Solvent = other solvents
| Solubility = slightly soluble
| SolubleOther = soluble in [[water]] and [[ethanol]] alcohol
}}
| Section3 = {{Chembox Structure
| CrystalStruct = tetragonal
}}
| Section4 =
| Section7 = {{Chembox Hazards
| Section5 NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 1}}
| Section6 =
| Section7 = {{Chembox Hazards
| NFPA-H = 2
| NFPA-F = 0
| NFPA-R = 1
| NFPA-S = OX
}}
}} '''Silver chlorate''' (AgClO<sub>3</sub>) forms white, tetragonal crystals.<ref>{{cite journal|last1=Náray-Szabó|first1=St. v.|last2=Pócza|first2=J.|title=Die Struktur des Silberchlorats AgClO3|journal=Zeitschrift für Kristallographie - Crystalline Materials|date=January 1942|volume=104|issue=1|pages=28–38 |doi=10.1524/zkri.1942.104.1.28|s2cid=102075872 |language=German}}</ref><ref>{{cite journal|last1=Deshpande|first1=Vilas|last2=Suryanarayana|first2=S V|last3=Frantz|first3=C|title=Tetragonal to cubic phase transition in silver chlorate|journal=Bulletin of Materials Science|date=December 1982|volume=4|issue=5|pages=563–568|doi=10.1007/BF02824963|doi-access=free}}</ref> Like all chlorates, it is water -soluble and an oxidizing agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed dark-coloured containers.
 
The substance exhibits [[brisance|blasting]] properties, therefore it is sometimes used as a primary explosive.
 
Silver(I) means silver is in its normal +1 [[oxidation state]].
 
==Production==
Silver chlorate is produced by the reaction of [[silver nitrate]] with [[sodium chlorate]] to produce both silver chlorate and [[sodium nitrate]].
 
Alternatively, it may be produced by the transmission of [[chlorine]] through a suspension of [[silver oxide]].
 
==See also==
Line 33 ⟶ 68:
 
==References==
{{Unreferenced|date =September 2007}}
{{reflist}}
 
{{Silver compounds}}
{{Chlorates}}
 
[[Category:Chlorates]]
[[Category:Silver compounds]]
[[Category:Oxidizing agents]]
 
{{inorganic-compound-stub}}
 
[[ar:كلورات فضة]]
[[fr:chlorate d'argent]]
[[ja:塩素酸銀]]
[[no:Sølvklorat]]
[[nl:Zilver(I)chloraat]]